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i have the same MP building in white-

it appears to be a tough gloss

while i kept mine stock, i painted the door and window trim-as well as dulling the plain medium grey roof-and painting the base to empahsize soild, rocks and planks-

my best guess would be to use a mineral based paint-ie flo quil, -or as mentioned a good primer-i think the key is mineral base as this seems to be what the white is and i think youll likely get better adhesion- i think that any water based paint will simply form droplets -even with detergent

if you really want to do it 'right'- then take the time to lightly sand the entire painted protions of the structure and then prime and paint
 
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